Fix: Excel – The File Could not be Accessed. Try One of the Following - Microsoft Word
If you try to save or open a Microsoft Word file you may receive the following error.
The file could not be accessed. Try one of the following:
*Make sure the specified folder exists
*Make sure the folder that contains the file is not read-only
*Make sure the file name does not contain any of the following characters
*Make sure the file/path name doesn’t contain more than 218 characters.
Microsoft states that if the path AND file name exceed 218 characters you may receive this error. Check to make sure this isn’t the case.
More info can be found here.